About
- Department: School of Physics and Electronic Science
- Gender: male
- Post:
- Graduate School:
- Degree: PhD
- Academic Credentials: Professor
- Tel:
- Email: bwhu@www.ozdabak.com
- Office:
- Address: Optics Building B519 (Dongchuan Road 500)
- PostCode:
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Education
BAC+MASTER, Fudan University, BAC+MASTER (Ping Zhou)
PhD, University of Lille I, Phd (JP Amoureux), National Centre for Ultra-High Field Nuclear Magnetic Resonance (Lille)
WorkExperience
2009.12-2014.7, Associate Professor
2014.8-2021.12, Professor
2018.7-present, Vice President of the School
2020.12-present, Deputy Director of Shanghai Key Laboratory of Magnetic Resonance
Resume
Hu Bingwen, Zijiang Professor in East China Normal University. Deputy director of Magnetic Resonance Sub-Association of China Association for Instrumental Analysis, senior editor of the Journal of Physical Chemistry Letters (July 2023- now), and Director of Engineering Research Center for Nanophotonics & Advanced Instrument (Ministry of Education) (2025), the deputy director of the Shanghai Key Laboratory of Magnetic Resonance (2020) and the deputy dean of the School of Physics and Electronic Science (2018).
He was the recipient of YuanZhi Outstanding Youth EPR award (2022) and Tianjuan Wang Magnetic Resonance Spectroscopy Award (2025). In 2024, Sino-French Joint Laboratory of Advanced Magnetic Resonance in Energy Chemistry was Established with the Institute of Precision Measurement, our group in East China Normal University, and the University of Lille. Established a joint laboratory was with Bruker (2025), a joint research center with NICE (2025). Have in-depth cooperation with CATL and Bruker.
He studied at Fudan University for bachelor's and master's degrees, and got PhD degree at the French Ultra high-Field Nuclear Magnetic Resonance Research Center at the University of Lille I, France, where he was engaged in the development of new NMR methods. After return to China, he focusses in the development of new technologies for NMR and EPR and their application in lithium-ion and sodium-ion battery systems. He was supported by the Excellent Youth Fund of the National Natural Science Foundation of China in 2015. In 2024, together with Wang Qiang (Institute of Precision Measurement Science and Technology Innovation, Chinese Academy of Sciences, referred to as the Institute of Precision Measurement), we successfully applied for the National Key R&D Program "Sino-French Joint Laboratory of Advanced Magnetic Resonance in Energy Chemistry", and a joint laboratory construction agreement was signed with the Institute of Precision Measurement, East China Normal University, and the University of Lille based on this program. He gave plenary talks at the 2014 and 2021 National Magnetic Resonance Conferences, and participated in the following important conferences and gave invited talks: 2022 Fall Meeting of the Chinese Physical Society (F Branch: Nano and Mesoscopic Physics ), 2023 33rd Congress of the Chinese Chemical Society, 2024 34rd Congress of the Chinese Chemical Society, 2024 Experimental Nuclear Magnetic Resonance Conference (ENC, 25 minutes) and APES（Asia-Pacific EPR/ESR Symposium, 25 minutes).
* Senior editor of the Journal of Physical Chemistry Letter * Director of Engineering Research Center for Nanophotonics & Advanced Instrument (Ministry of Education) * Deputy director of the Shanghai Key Laboratory of Magnetic Resonance * Recipient of YuanZhi Outstanding Youth EPR award * Recipient of Tianjuan Wang Magnetic Resonance Spectroscopy Award
* Deputy dean of the School of Physics and Electronic Science * chairman of the Physics Academic Degree Evaluation Committee * member of the 12th Academic Degree Evaluation Committee of ECNU
Other Appointments
Academic organization: Senior Editor of Journal of Physical Chemistry Letters, Editorial Board Member of Journal of Functional Materials and Devices, Editorial Board Member oof Magnetic Resonance Letters
Social services: National Foundation Correspondence Review; Evaluations of excellent youth/key/general projects; major project review; Germany/Switzerland/France/Czech Republic Foundation Correspondence Review; Provincial and municipal award review
Research Fields
(1) Magnetic resonance imaging (MRI) technology and electron paramagnetic resonance (EPR) imaging technology to study the materials of lithium-ion batteries (including solid electrolytes)
(2) In situ/ex situ solid NMR, in situ/ex situ EPR for the materials of lithium-ion batteries (including solid electrolytes)
(3) Development of new methods for solid-state NMR and new methods for EPR
(4) First-principles calculation of solid-state NMR and EPR ===================
Solid-state NMR capabilities:
(1) In situ technology (2) pulse development capabilities, such as IR-pj-MATPASS, DQ-HMQC;
(3) Extensive nuclear detection capabilities, such as 17O, 59Co, 51V and other special nuclei;
EPR capabilities:
(1) In situ technology and in situ imaging (2) Special-species detection capabilities, such as molecular oxygen O2
(3) the analytical ability, combined with condensed matter physics
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Dissertation： | Number | Title | Author | Type | Date | | 1 | Toward an Understanding of the Mechanism of Lithium Plating and Stripping via In Situ ESR Imaging | Geng Fushan | Postdoctoral | 2023/6/1 | | 2 | Magnetic Resonance Study on NaxA1-yMnyO2 (A = Mg, Zn) cathode materials based on oxygen valence variation | Chen Chen | Master | 2023/5/15 | | 3 | NMR Characterization and Ion Loss Studies of Cathode Materials for Sodium Ion Batteries | Liao Yuxin | doctor | 2023/5/10 | | 4 | Solid-state NMR study of high-voltage LiCoO2 and its doped product | Gu Suyu | Master | 2023/4/20 | | 5 | Magnetic Resonance Study of Li, Mn-Based Layered Oxide Cathode Materials Based on Oxygen Anion Redox | Liu Hui | doctor | 2023/3/22 | | 6 | Anionic Redox Mechanism Study of Sodium-ion Layered Oxide Cathode Materials | Zhao Chong | doctor | 2022/3/7 | | 7 | Research on reactive oxygen species of the Lithium-air battery by Electron Paramagnetic Resonance | Lin Yang | Master | 2022/3/1 | | 8 | Magnetic Resonance Study on the Charge/Discharge Mechanism of Cathode Materials for Sodium Ion Batteries | Qiu Qing | Master | 2022/3/1 | | 9 | MAGNETIC RESONANCE IMAGING STUDY OF GRANULAR PACKING PROBLEMS | Xia Chengjie | Postdoctoral | 2021/11/30 | | 10 | Research on Visualization of the Sedimentation Process of Polydopamine Nanoparticles | Wang Shaoyan | Master | 2021/4/12 | | 11 | Adjusting the distribution of gold nanoparticles in core-shell structure and the application in photoluminescence | Zhang wei | Master | 2021/4/10 | | 12 | The Study of Battery Materials via Nuclear Magnetic Resonance and Electron Paramagnetic Resonance | Geng Fushan | doctor | 2021/4/10 | | 13 | Modification and Redox Chemistry Mechanism of Layered Oxide Cathode Materials for Lithium/Sodium Ion Batteries | Hu Bei | doctor | 2021/3/10 | | 14 | Synthesis and Mechanism Studies of Layered Oxide Cathode Materials for Lithium/Sodium-Ion Batteries | Wang Jianyin | Master | 2020/5/1 | | 15 | Studies on Magnetic Resonance Imaging Reconstruction and Computer-aided Diagnosis based on Artificial Intelligence | Song Yang | doctor | 2019/5/10 | | 16 | Synthesis and Properties of High-Performance Layered Lithium-Rich Cathode Materials for Lithium Ion Batteries | Yang Mengchu | Master | 2019/5/8 | | 17 | Design, Synthesis and Modification of new-type Metal-Organic Frameworks (MOFs) as Cathodes or Anodes Materials for Lithium Ion Batteries | Lou Xiaobing | doctor | 2019/5/1 | | 18 | The Synthesis of Nanoporous Carbon Material and Applications in Lithium Oxygen Batteries | Ge Qiong | Master | 2019/4/1 | | 19 | Research on Cathode and Anode Materials of Lithium-Ion Batteries Based on Metal-Organic Frameworks | Wang Peng | Master | 2019/3/21 | | 20 | The Application of Cobalt Based Metal-Organic Framework Anodes in Lithium/Sodium Ion Batteries | Ning Yanqun | Master | 2018/6/6 | | 21 | The Application of Metal-Organic Frame Materials and Its Derived Phosphate in Lithium-ion Batteries | Liao Yuxing | Master | 2018/5/20 | | 22 | New Solib-state Nuclear Magnetic Resonance methods and their applications in battery materials | Shen Ming | Postdoctoral | 2018/4/1 | | 23 | The Redox Chemistry Studies of Metal-Organic Framework Anodes and Fluorophosphate Cathode by the Combination of NMR, EPR, and Synchrotron Radiation Techniques | Li Chao | Doctor* | 2018/5/1 | | 24 | Design, Synthesis and Electrochemical Properties of Metal-Organic Framework and its Derived Transition-Metal Oxide as Anode Materials for Lithium Ion Batteries | Hu Xiaoshi | Doctor* | 2018/5/1 | | 25 | Application of Metal Organic Framework Materials Based on 1,4-benzenedicarboxylic Acid Ligands in Lithium-ion Batteries | Hu Huiping | Master | 2017/5/31 | | 26 | The Application of Bimetallic Organic Framework for Lithium-ion Batteries | Li Tian | Master | 2017/4/10 | | 27 | Solid-state NMR for 15N-15N correlations and PEO/urea/alkali salts ternary solid polymer electrolytes | Yan Xiaojing | Master | 2016/6/28 | | 28 | New solid-state NMR methods and MOF anode materials | Peng Bo | Master | 2016/6/22 | | 29 | New solid-state NMR methods for homo-/hetero-nuclear correlations and spin=1 nucleus | Shen Ming | Doctor* | 2015/3/1 | | 30 | New pulse sequences for heteronuclear experiments and covariance for homonuclear experiments in SS-NMR | Li Yixuan | Doctor* | 2015/3/1 | | 31 | Preparation、characterization 、catalytic study of microporous palladium-loading MOFs as heterogeneous catalysts and study of covariance NMR spectroscopy | Qian Yi | Master | 2015/4/1 | | 32 | Solid-State NMR studies for poly(ethyl oxide)/LiAsF6 cyrstalline polymer electrolytes in solid lithium batteries | Liu Qinghua | Doctor* | 2014/3/1 | | 33 | Application of the NMR techniques in structural analysis of polysaccharides | Wang Linqiang | Master | 2013/4/1 | | 34 | Phase structures and segmental dynamics of poly(Ethylene Oxide)/LiCF3SO3 complexes as studied by solid-state high-resolution 13C nuclear magnetic resonance | Wei Ling | Doctor* | 2013/5/1 | | 35 | Design of heterogenous palladium catalyst on basis of solid-state NMR structural characterization | Zhang Siyong | Doctor* | 2013/4/1 |
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| *: Co-instruction with Prof. Chen Qun |
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Scientific
2022: National Foundation /NSFC - General Project
2018: National Foundation /NSFC - General Project
2015: NSFC-Outstanding Youth Fund Project
2013: National Foundation /NSFC - General Project
2011: National Foundation /NSFC - Youth Project
Academic Achievements
Webinar about our research: https//www.bruker.com/en/news-and-events/webinars/2023/magnetic-
https://www.bilibili.com/video/BV16fwheDEe2/?spm_id_from=333.337.search-card.all.click&vd_source=39693f5de25dbec4635f2692a4b3fd3d
Publications：https://publons.com/researcher/1585448/bingwenhu/
https://www.researchgate.net/profile/Bingwen_Hu/publications Short review: https://jelectrochem.xmu.edu.cn/journal/vol28/iss2/7/ https://www.whxb.pku.edu.cn/EN/10.3866/PKU.WHXB201902019 =================================================================================== * EPR + NMR with cathode
The development of EPR has become an important tool for the characterization of molecular oxygen. Coexistence of (O2)n− and Trapped Molecular O2 as the Oxidized Species in P2-Type Sodium 3d Layered Oxide and Stable Interface Enabled by Highly Fluorinated Electrolyte, Journal of the American Chemical Society 143(44) (2021) 18652-18664.
EPR showed that RIXS could not distinguish between molecular oxygen and oxygen dimer dimers, and found that Sn-O-O ionic bonds were easily broken to form molecular oxygen. 4d Lithium-Rich Cathode System Reinvestigated with Electron Paramagnetic Resonance: Correlation between Ionicity, Oxygen Dimers, and Molecular O2，2023，The Journal of Physical Chemistry Letters 14(34):7711−7717
The combination of EPR, NMR and SQUID showed that in the Li2RuO3 system, strong magnetic resistance frustration was the main driving force for the generation of molecular oxygen. Coupling of oxygen dimer and trapped O2 with strong magnetic frustration in layered Li-rich Cathodes ACS Energy Lett. 2025, 10, 1, 459–468
It was found that both O2 and O3 structures generate molecular oxygen; Coincident formation of trapped molecular O2 in oxygen-redox-active archetypical Li 3d oxide cathodes unveiled by EPR spectroscopy，Energy Storage Materials ，DOI: 10.1016/ j.ensm.2022.05.011
It was found that in the Ti-doped NLMO system, Li could be reinserted in the TM layer, and the oxygen reaction was more reversible. Unraveling the Critical Role of Ti Substitution in P2-NaxLiyMn1-yO2 Cathode for Highly Reversible Oxygen Redox Chemistry，2020，Chemistry of Materials ，DOI: 10.1021/acs.chemmater.9b03765
In the cation-disorder system, 17O NMR and EPR were used to find that the reversibility of oxygen reaction was poor and the migration and aggregation of Mn was confirmed. Anionic Redox and Structural Degradation in Cation-Disordered Rock-Salt Li1.2Ti0.4Mn0.4O2 Cathode Material Revealed by Solid-State NMR and EPR，2020，Journal of Materials Chemistry A 8(32)， DOI: 10.1039/D0TA03358H * EPR Imaging
Three-dimensional in-situ emmetropic imaging was developed for the precipitation imaging of Cr5+. Operando EPR and EPR Imaging Study on a NaCrO2 Cathode: Electronic Property and Structural Degradation with Cr Dissolution， 2021，The Journal of Physical Chemistry Letters 12(2):781–786，DOI: 10.1021/acs.jpclett.0c03327
In situ front-view EPR imaging was developed for use in LCO|Cu system, the inhomogeneity of lithium deposition was found. Mapping the Distribution and the Microstructural Dimensions of Metallic Lithium Deposits in an Anode-Free Battery by In Situ EPR Imaging，2021，Chemistry of Materials 33(21)，DOI: 10.1021/ acs.chemmater.1c02323
EPR imaging of graphite was realized; Quantitative Operando EPR Method on Graphite Anodes: Electronic Properties, Lithiation Kinetics, and Lithium Deposition， 2024，Chemistry of Materials 36(9)，DOI: 10.1021/ acs.chemmater.4c00152
The imaging of lithium dendrites on graphite was realized, and it was found that the overcharge leads to long dendrites. Visualizing Lithium Deposition and Identifying Two Types of Dendrites in Extreme-Fast-Charging Full Cells across the Entire Lifespan by Operando EPR and EPR Imaging，2024，Journal of Physical Chemistry 15(50):12248–12256，DOI: 10.1021/acs.jpclett.4c03022
The in-situ EPR imaging of solid-state batteries was realized, and the A/B imaging technology was developed, and the pressure was high while the deposition area was large. All-Solid-State Batteries with Pre-plated Ultrathin Lithium Metal Enabled by No Pressure Holding and Characterized by In Situ Electron Paramagnetic Resonance Imaging，2023，The Journal of Physical Chemistry Letters 14(20):4682–4687，DOI: 10.1021/acs.jpclett.3c00906
The in-situ L-band imaging of solid-state batteries was realized, and the relationship between lithium deposition and pressure was discovered, and the circular lithium sheet was replaced by a ring lithium sheet. A Ring-Shaped Lithium Metal Anode Enables High-Performance All-Solid-State Batteries Revealed by In Situ L‑Band EPR Imaging，2025， Journal of Physical Chemistry 16:917-923，DOI: 10.1021/ acs.jpclett.4c03585
EPR imaging of sodium metal deposition was realized, and central aggregation behavior and progressive self-leveling behavior were discovered. Progressive Self-Leveling Deposition Improves the Cyclability of Anode-less Sodium Metal Batteries Revealed by In Situ EPR Imaging，2024，ACS Energy Letters 9(4):1633–1638，DOI: 10.1021/ acsenergylett.4c00021
* EPR vs. Lithium Air
In-situ EPR observation of lithium air showed that Co3O4 could eliminate LiO2. Suppressing Singlet Oxygen Formation during the Charge Process of Li-O2 Batteries with a Co3O4 Solid Catalyst Revealed by Operando Electron Paramagnetic Resonance，2021，The Journal of Physical Chemistry Letters 12:10346，DOI: 10.1021/acs.jpclett.1c02928
In-situ EPR observation, using Co-ATP to achieve the LiOH path, and can eliminate 1O2. Completely Eradicating Singlet Oxygen in Li–O2 Battery via Cobalt(II)-Porphyrin Complex-Catalyzed LiOH Chemistry，2023，The Journal of Physical Chemistry Letters 14(4):846-853，DOI: 10.1021/acs.jpclett.2c03683
* Parallel-Mode EPR Parallel-Mode EPR was used for high-spin Co2+. The study of electrochemical cycle for LiCoO2 by dual-mode EPR, Magnetic Resonance Letters (2023) https://doi.org/10.1016/j.mrl.2022.04.002. Parallel-Mode EPR was used to probe V3+. Unraveling the Redox Couples of VIII/VIV Mixed-Valent Na3V2(PO4)2O1.6F1.4 Cathode by Parallel-Mode EPR and In Situ/Ex Situ NMR, The Journal of Physical Chemistry C 122(48) (2018) 27224-27232.Carbon-coated Li3V2(PO4)3 derived from metal-organic framework as cathode for lithium-ion batteries with high stability, Electrochimica Acta 271 (2018) 608-616. * 17O and 59Co NMR 17O and 59Co NMR for LiCoO2, Monitoring the evolution of local oxygen environments during LiCoO2 charging via ex situ 17O NMR, Chemical Communications 55(52) (2019) 7550-7553. 17O NMR for all-solid-batteries. Probing the degradation of LiCoO2 in batteries subjected to high-voltage cycling with 17O solid-state NMR spectroscopy. Chemical Communications 2023. 59Co NMR for for all-solid-batteries for .Distinguishing the Effects of the Space-Charge Layer and Interfacial Side Reactions on Li10GeP2S12-Based All-Solid-State Batteries with Stoichiometric-Controlled LiCoO2, ACS Applied Materials & Interfaces (2022).
* NMR method
Using ball mills, T1 is greatly reduced. Reduction of the 13 C cross-polarization experimental time for pharmaceutical samples with long T1 by ball milling in solid-state NMR
Development of 14N Overtone technology for 1H-14N DMQC. Composite pulses in directly and indirectly detected 14N MAS overtone spectroscopy
Development of RFDR-XY8-M4 super-phase cycling。Broadband finite-pulse radio-frequency-driven recoupling (fp-RFDR) with (XY8)4(1) super-cycling for homo-nuclear correlations in very high magnetic fields at fast and ultra-fast MAS frequencies；
Development of SHA+/SHANGHAI pulse trains for measuring long distances of 13C-13C. Broad-band homo-nuclear correlations assisted by (1)H irradiation for bio-molecules in very high magnetic field at fast and ultra-fast MAS frequencies；Very-Long-Distance Correlations in Proteins Revealed by Solid-State NMR Spectroscopy；
Development of RSDF for the distinction between soft and hard polymer segments. Rotor-synchronized dipolar-filter sequence at fast MAS in solid-state NMR
==================================================================================== Typical Papers：（Underlined papers are selected papers）
（1）EPR-NMR # EPR for metal-ion batteries (including in-situ EPR and in-situ EPR imaging) * Jiang, Y.; Lu, G.; Kang, S.; Geng, F.; Hu, B., All-Solid-State Batteries with Pre-plated Ultrathin Lithium Metal Enabled by No Pressure Holding and Characterized by In Situ Electron Paramagnetic Resonance Imaging. The Journal of Physical Chemistry Letters 2023, 14 (20), 4682-4687.
* Feng, H.; Yang, Q.; Li, C.; Lin, Y.; Liu, H.; Zhang, N.; Hu, B., Completely Eradicating Singlet Oxygen in Li–O2 Battery via Cobalt(II)-Porphyrin Complex-Catalyzed LiOH Chemistry. The Journal of Physical Chemistry Letters 2023, 14 (4), 846-853. * H. Liu, C. Li, C. Zhao, W. Tong, B. Hu, Coincident formation of trapped molecular O2 in oxygen-redox-active archetypical Li 3d oxide cathodes unveiled by EPR spectroscopy, Energy Storage Materials 50 (2022) 55-62. * B. Hu, F. Geng, M. Shen, B. Hu, The study of electrochemical cycle for LiCoO2 by dual-mode EPR, Magnetic Resonance Letters (2023) https://doi.org/10.1016/j.mrl.2022.04.002. * C. Zhao, C. Li, H. Liu, Q. Qiu, F. Geng, M. Shen, W. Tong, J. Li, B. Hu, Coexistence of (O2)n− and Trapped Molecular O2 as the Oxidized Species in P2-Type Sodium 3d Layered Oxide and Stable Interface Enabled by Highly Fluorinated Electrolyte, Journal of the American Chemical Society 143(44) (2021) 18652-18664. * F. Geng, Q. Yang, C. Li, M. Shen, Q. Chen, B. Hu, Mapping the Distribution and the Microstructural Dimensions of Metallic Lithium Deposits in an Anode-Free Battery by In Situ EPR Imaging, Chemistry of Materials 33(21) (2021) 8223-8234. * Y. Lin, Q. Yang, F. Geng, H. Feng, M. Chen, B. Hu, Suppressing Singlet Oxygen Formation during the Charge Process of Li-O2 Batteries with a Co3O4 Solid Catalyst Revealed by Operando Electron Paramagnetic Resonance, The Journal of Physical Chemistry Letters 12(42) (2021) 10346-10352. * B. Hu, F. Geng, M. Shen, C. Zhao, Q. Qiu, Y. Lin, C. Chen, W. Wen, S. Zheng, X. Hu, C. Li, B. Hu, A multifunctional manipulation to stabilize oxygen redox and phase transition in 4.6 V high-voltage LiCoO2 with sXAS and EPR studies, Journal of Power Sources 516 (2021) 230661. * F. Geng, Q. Yang, C. Li, B. Hu, C. Zhao, M. Shen, B. Hu, Operando EPR and EPR Imaging Study on a NaCrO2 Cathode: Electronic Property and Structural Degradation with Cr Dissolution, The Journal of Physical Chemistry Letters 12(2) (2021) 781-786. * Y. Liao, C. Li, X. Lou, X. Hu, Y. Ning, F. Yuan, B. Chen, M. Shen, B. Hu, Carbon-coated Li3V2(PO4)3 derived from metal-organic framework as cathode for lithium-ion batteries with high stability, Electrochimica Acta 271 (2018) 608-616. * C. Li, X. Lou, Q. Yang, Y. Zou, B. Hu, Remarkable improvement in the lithium storage property of Co2(OH)2BDC MOF by covalent stitching to graphene and the redox chemistry boosted by delocalized electron spins, Chemical Engineering Journal 326 (2017) 1000-1008. * C. Li, X. Lou, M. Shen, X. Hu, W. Yan, Y. Zou, W. Tong, B. Hu, High-capacity cobalt-based coordination polymer nanorods and their redox chemistry triggered by delocalization of electron spins, Energy Storage Materials 7 (2017) 195-202.
# NMR for metal-ion batteries (including in-situ NMR) * Lu, G.; Geng, F.; Guo, N.; Yao, S.; Shen, M.; Hu, B., Probing the degradation of LiCoO2 in batteries subjected to high-voltage cycling with 17O solid-state NMR spectroscopy. Chemical Communications 2023. * Liao, Y.; Feng, H.; Yang, Q.; Shen, M.; Jiang, Y.; Li, C.; Zhao, C.; Geng, F.; Hu, B., Oxygen Redox Activation at Initial Cycle to Improve Cycling Stability for the Na0.83Li0.12Ni0.22Mn0.66O2 System. ACS Applied Materials & Interfaces 2023, 15 (8), 10709-10717. * G. Lu, F. Geng, S. Gu, C. Li, M. Shen, B. Hu, Distinguishing the Effects of the Space-Charge Layer and Interfacial Side Reactions on Li10GeP2S12-Based All-Solid-State Batteries with Stoichiometric-Controlled LiCoO2, ACS Applied Materials & Interfaces (2022).
* C. Zhao, C. Li, Q. Yang, Q. Qiu, W. Tong, S. Zheng, J. Ma, M. Shen, B. Hu, Anionic redox reaction in Na-deficient layered oxide cathodes: Role of Sn/Zr substituents and in-depth local structural transformation revealed by solid-state NMR, Energy Storage Materials 39 (2021) 60-69. * Q. Qiu, C. Li, H. Liu, Y. Liao, C. Zhao, F. Geng, M. Shen, J. Li, W. Tong, B. Hu, NMR Evidence for the Multielectron Reaction Mechanism of Na3V2(PO4)3 Cathode and the Impact of Polyanion Site Substitution, J. Phys. Chem. C 125(28) (2021) 15200-15209. * Y. Liao, C. Li, F. Geng, M. Shen, B. Hu, Na3V2(PO4)3 Revisited: A High-Resolution Solid-State NMR Study, The Journal of Physical Chemistry C 125(43) (2021) 24060-24066. * B. Hu, X. Lou, C. Li, F. Geng, C. Zhao, J. Wang, M. Shen, B. Hu, Reversible phase transition enabled by binary Ba and Ti-based surface modification for high voltage LiCoO2 cathode, Journal of Power Sources 438 (2019) 226954. * F. Geng, M. Shen, B. Hu, Y. Liu, L. Zeng, B. Hu, Monitoring the evolution of local oxygen environments during LiCoO2 charging via ex situ 17O NMR, Chemical Communications 55(52) (2019) 7550-7553.
# EPR & NMR for metal-ion batteries * C. Li, C. Zhao, B. Hu, W. Tong, M. Shen, B. Hu, Unraveling the Critical Role of Ti Substitution in P2-NaxLiyMn1–yO2 Cathodes for Highly Reversible Oxygen Redox Chemistry, Chemistry of Materials 32(3) (2020) 1054-1063.
* F. Geng, B. Hu, C. Li, C. Zhao, O. Lafon, J. Trébosc, J.-P. Amoureux, M. Shen, B. Hu, Anionic redox reactions and structural degradation in a cation-disordered rock-salt Li1.2Ti0.4Mn0.4O2 cathode material revealed by solid-state NMR and EPR, Journal of Materials Chemistry A 8(32) (2020) 16515-16526. * C. Li, M. Shen, X. Lou, B. Hu, Unraveling the Redox Couples of VIII/VIV Mixed-Valent Na3V2(PO4)2O1.6F1.4 Cathode by Parallel-Mode EPR and In Situ/Ex Situ NMR, The Journal of Physical Chemistry C 122(48) (2018) 27224-27232.
（2）Solid-state NMR：
• Broad-band homo-nuclear correlations assisted by (1)H irradiation for bio-molecules in very high magnetic field at fast and ultra-fast MAS frequencies； • Broadband finite-pulse radio-frequency-driven recoupling (fp-RFDR) with (XY8)4(1) super-cycling for homo-nuclear correlations in very high magnetic fields at fast and ultra-fast MAS frequencies； • Very-Long-Distance Correlations in Proteins Revealed by Solid-State NMR Spectroscopy； • Composite pulses in directly and indirectly detected 14N MAS overtone spectroscopy • Reduction of the 13 C cross-polarization experimental time for pharmaceutical samples with long T1 by ball milling in solid-state NMR；
（3）NMR for polymer elctrolytes：
• Phase Structure and Helical Jump Motion of Poly(ethylene oxide)/LiCF3SO3 Crystalline Complex: A High-Resolution Solid-State C-13 NMR Approach； • Polymer chain diffusion and Li+ hopping of poly(ethylene oxide)/LiAsF6 crystalline polymer electrolytes as studied by solid state NMR and ac impedance； • PEO-urea-LiTFSI ternary complex as solid polymer electrolytes；
（4）DFT：
• Optimizing the U_eff value for DFT+U calculation of paramagnetic solid-state NMR shifts by double Fermi-contact-shift verification
（5）Review * B.-W. Hu, C. Li, F.-S. Geng, M. Shen, Magnetic Resonance in Metal-Ion Batteries: From NMR (Nuclear Magnetic Resonance) to EPR (Electron Paramagnetic Resonance), Journal of Electrochemistry 28(2) (2022) 2108421. * F. Geng, B. Peng, Y. Yao, Q. Chen, B. Hu, Chapter Six - Solid-state NMR studies on crystalline solid polymer electrolytes and important cathode materials for lithium-ion batteries, in: G.A. Webb (Ed.), Annual Reports on NMR Spectroscopy, Academic Press, 2020, pp. 265-308.
Honor
2025: Tianjuan Wang Magnetic Resonance Spectroscopy Award 2022: YuanZhi Outstanding Youth EPR award 2010: Prix de thèse "Sciences et technologies" awarded by Consortium of seven universities in Nord-de-France
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